Butane-1,4-diamine zinc(II) hydrogen phosphite

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Butane-1,4-diamine zinc(II) hydrogen phosphite.

The title compound, poly[zinc(II)-mu-butane-1,4-diamine-mu-(hydrogen phosphito)] (C(4)H(12)N(2))(0.5)[ZnHPO(3)], is a hybrid organic-inorganic solid built up from 1,4-diaminobutane molecules, Zn(2+) cations (coordinated by three O atoms and one N atom) and HPO(3)(2-) hydrogen phosphite groups. The organic species bonds to the Zn atom as an unprotonated ligand, resulting in it acting as a bridge...

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N,N′-Bis(3,4-dimethoxy­benzyl­idene)butane-1,4-diamine

The title Schiff base compound, C(22)H(28)N(2)O(4), was synthesized by the reaction of 3,4-dimethoxy-benzaldehyde and 1,4-diamino-butane in methanol. The mol-ecule is located on a center of inversion with one half-mol-ecule in the asymmetric unit. Both C=N double bonds are in a trans configuration. Inter-molecular C-H⋯O hydrogen bonds link the mol-ecules into a three-dimensional network.

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N,N′-Bis(4-bromo­benzyl­idene)butane-1,4-diamine

The mol-ecule of the title Schiff base compound, C(18)H(18)Br(2)N(2), lies across a crystallographic inversion centre and adopts an E configuration with respect to the C=N bond. In the crystal structure, mol-ecules are linked into chains along [201] through inter-molecular Br⋯Br inter-actions [3.3747 (3) Å], which are significantly shorter than the sum of the van der Waals radii for Br atoms (3...

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Hydrogen bonding in cytosinium dihydrogen phosphite

In the title compound, C(4)H(8)N(3)O(4)P(+)·H(2)PO(3) (-), the cytosine mol-ecule is monoprotonated and the phospho-ric acid is in the monoionized state. Strong hydrogen bonds, dominated by N-H⋯O inter-actions, are responsible for cohesion between the organic and inorganic layers and maintain the stability of this structure.

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6-Methyl-1,3,5-triazine-2,4-diamine butane-1,4-diol monosolvate

The title co-crystal, C4H7N5·C4H10O2, crystallizes with one mol-ecule of 6-methyl-1,3,5-triazine-2,4-diamine (DMT) and one mol-ecule of butane-1,4-diol in the asymmetric unit. The DMT mol-ecules form ribbons involving centrosymmetric R2(2)(8) dimer motifs between DMT mol-ecules along the c-axis direction. These ribbons are further hydrogen bonded to each other through butane-1,4-diol, forming s...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section C Crystal Structure Communications

سال: 2004

ISSN: 0108-2701

DOI: 10.1107/s0108270104024862